Heated and circulated premixed saltwater storage, how long will it last? - BRStv Investigates
We looked at the effects of heating and circulating premixed saltwater during storage by monitoring calcium and alkalinity levels over a 2 week period. We also observed the amount of precipitate leftover inside the container. We then compared the results with what we found previously during our BRS Investigates How long can I store saltwater after mixing? with the goal of providing you with the best methods for storing saltwater at home.
We aim to answer two questions:
- 1. Do parameters like alkalinity and calcium shift in heated and well circulated reservoirs?
- 2. Will we see any related precipitation or crust in the bins after storage?
We all desire stable numbers for Alkalinity and Calcium and if given the choice we’d rather not have to adjust those levels in our mixing bins prior to using the saltwater for our regular water changes.
Additionally, we look at precipitate in the containers after mixing in hopes of finding ways to reduce the amount of cleaning required to maintain storage reservoirs.
The Test Experiment
We tested our eight most popular salt mix brands that we also used in the previous test:
- Instant Ocean Reef Crystals
- Instant Ocean Standard
- Red Sea Blue Bucket
- Red Sea Coral Pro
- HW Reefer
- Brightwell Aquatics NeoMarine
- Tropic Marine Classic
- Tropic Marine Pro Salts
We mixed 20 gallons of each salt mix with RO/DI water to the commonly targeted 35 parts per thousand (PPT) or 1.026 Specific Gravity.
A 100 watt Finnex HPG Heater and Maxi-Jet 1200 water pump was placed inside each testing container to reach a target temperature of 78 degrees F and circulate the water inside.
Some salt mix brands directly state to mix cold then heat to the desired temperature so we started at a room temp of around 68 degrees F and then slowly heated to a common target temperature of 78 degrees F over the course of the first 24 hours.
Each testing container was also loosely covered in plastic wrap to eliminate any debris from falling into the containers and reduce evaporation rates.
We tested the calcium and alkalinity levels upon initial mixing and then in varying increments thereafter up to a maximum of two weeks using the same type of hobby grade test kits that many reefers use at home.
We accounted for an accuracy margin in the test results of +/- 0.5 dKH for Alkalinity and +/- 15 parts per million(PPM) in calcium levels. This accuracy range is not only within the test-kits’ advertised accuracy range, but also adds some room for minor human inconsistencies and somewhat subjective endpoint interpretations.
The Results
In theory, the solubility of calcium carbonate actually decreases as the solution temperature rises. Therefore, we expected more precipitate compared to unheated and uncirculated saltwater which we tested in a previous BRStv Investigates. The results here were surprising to say the least which we address after going through the test results.
Looking at calcium, in almost every case there is a steady line of stable levels for each salt mix with no drastic drops over the two weeks and actually a very slight increase in levels towards the end for a majority.
When interpreting the results, we focus on the data taken at 24 Hours to 2 Weeks because it takes up to 24 hours for the saltwater to be fully homogenized.
We confirmed this by looking at the common trends in which all of the salts took somewhere between 6 and 24 hours to stabilize.
Furthermore, this was made visually evident in another BRStv Investigates Video where we tested for clarity and contrast. All of the same salt mixes tested in this video required 8 or more hours to mix clear. Tropic Marin Pro being the best which mixed clear in about 8 hours and produced a stable 420 PPM of calcium after 24 hours.
Tropic Marin Pro
Change in Calcium levels when stored for two weeks
390ppm - 420ppm
Tropic Marin Classic
Change in Calcium levels when stored for two weeks
400ppm - 410ppm
Brightwell Aquatics Neo-Marine
Change in Calcium levels when stored for two weeks
380ppm - 400ppm
HW Reefer
Change in Calcium levels when stored for two weeks
No change - 430ppm
Red Sea Blue Bucket
Change in Calcium levels when stored for two weeks
420ppm - 430ppm
The Red Sea Coral Pro
Change in Calcium levels when stored for two weeks
450ppm - 460ppm
Instant Ocean Standard
Change in Calcium levels when stored for two weeks
415ppm - 425ppm
Instant Ocean Reef Crystals
Change in Calcium levels when stored for two weeks
490ppm - 500ppm
None of the salts dropped like what we found in our first storage test. None of the tanks show signs of precipitate nearly to the degree we had at the end of our previous test (if any at all)!
The most dramatic results show that with elevated salts like the Red Sea Coral Pro we can see a major difference in levels over weeks of storage. It is notable that the mixing procedure for Coral Pro explicitly states to mix it first, then heat as we have done, yet for this test we went well beyond the maximum 4hrs of mixing they advise.
Moving onto Alkalinity levels and comparing the same 24hr to 2week window the results show that each salt mix looks to be very stable across the board.
Tropic Marin Pro
Change in Alkalinity when stored for two weeks
7.1 - 7.2 dKH
Tropic Marin Classic
Change in Alkalinity when stored for two weeks
No Change - 9.5 dKH
Brightwell Aquatics Neo-Marine
Change in Alkalinity when stored for two weeks
No change - 7.8 dKH
HW Reefer
Change in Alkalinity when stored for two weeks
9.0 - 9.3 dKH
Red Sea Blue Bucket
Change in Alkalinity when stored for two weeks
8.0 - 8.1 dKH
Red Sea Coral Pro
Change in Alkalinity when stored for two weeks
12.1 - 12.4 dKH
Instant Ocean Standard
Change in Alkalinity when stored for two weeks
No change - 10.3 dKH
Instant Ocean Reef Crystals
Change in Alkalinity when stored for two weeks
No Change - 10.8dKH
Absolutely no denying the stability of carbonate hardness for all of the salt mixes with a majority staying very stable through the 2 week storage test.
Again the elevated salt mixes having dramatically different results than previous tests without heat and circulation.
Another interesting point is the Calcium Carbonate precipitate left over in the mixing containers was far less than what we saw previously which at face value kind of defies what we felt should be happening considering we added heat to the equation.
Does the Alkalinity and Calcium parameters shift in heated and well circulated saltwater storage?
We give this a ONE on the reef fantasy scale, because the levels for both Alkalinity and Calcium remained very stable except for some slight increase in Calcium as the mix becomes completely dissolved. This minor increase in calcium could also be a result of using hobby grade test kits.
Did we notice any precipitation or crust in the bins after storage?
We definitely don’t see precipitate to the degree that we did in the first BRStv Investigates test in which the saltwater was stored without a heater or water pump. This begins to raise even more questions about why and how that may be and what we are actually seeing considering we know that heat will decrease the solubility of calcium carbonate in water.
Conclusion
Depending on the salt mix you use, it might be worthwhile to heat and circulate your saltwater during storage. Especially for salt mixes that contain elevated levels for reef tanks or clearly state in the instructions how to mix properly (Red Sea Coral Pro). That said, there are some salt options that maintain steady parameters and don’t require heating and circulating while being stored which equate to reduced electricity consumption.
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